Ok, so after cooling myself down having wasted nearly my entire day trying to troubleshoot this thing. With the stock cooler reinstalled, I'm able to preinstall the iCUE software.
What I did next was take the H150 back out of the box, I was preparing to ship back to Amazon and plugged it back into power, the AIO PUMP header on the motherboard, the fans it came with, and the USB header on the MOBO.
Rebooting, the iCUE detects the H150 however oddly shows 0rpm fan speed and 0rpm pump speed even when seemingly setting them all into whatever "EXTREME" mode means.
Is this thing just defective?
EDIT: The stock cooler and fan are still on top of the CPU, so that I can actually boot up my PC and run the iCUE software.