Since there is a bunch of posts and replies of people asking for H100i RGB Pro XT firmware file... I uploaded the one I used to manually upgrade to latest firmware.
https://www.mediafire.com/file/7bz9kf3fhtujffb/CUEGxaulj%257Bd666be6f-b520-490c-92cc-8f9e2442d0cc%257D_temp_H100I_Pro_XT_V1.1.32.hex/file
The method to manually flash the firmware is in this video provided by Corsair:
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If the above fails, try turning off your computer and shutting down the power supply and drain the remaining energy and try again (it didn't work for me after the iCue failed update till I shutdown, turned off PSU and drained all the energy). This caused the H100i to function correctly on older firmware and was able to update right away.
If it still fails, try doing the manual flashing process in Windows 10 Safe mode.
How to boot Windows 10 in Safe Mode:
https://www.dell.com/support/article/en-ca/sln306359/how-to-boot-to-safe-mode-in-windows-10?lang=en